Crystal structure of (E)-2-[3-(tert -butyl)-2-hydroxybenzylidene]- N -cyclohexylhydrazine-1-carbothioamide

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Abstract

In the title compound, C 18 H 27 N 3 OS, the cyclohexane ring has a chair conformation. The azomethine C=N double bond has an E configuration. The nearly planar hydrazinecarbothioamide moiety and substituted benzene ring are twisted by 31.13 (5)° relative to each other. The amide moiety and the cyclohexane ring are almost perpendicular to each other; a similar conformation was previously observed in reported structures. In the crystal, molecules are linked by N - H⋯S hydrogen bonds, forming inversion dimers with an R 2 2 (8) ring motif.

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Arafath, M. A., Kwong, H. C., Adam, F., & Razali, M. R. (2018). Crystal structure of (E)-2-[3-(tert -butyl)-2-hydroxybenzylidene]- N -cyclohexylhydrazine-1-carbothioamide. Acta Crystallographica Section E: Crystallographic Communications, 74, 1460–1462. https://doi.org/10.1107/S2056989018013129

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