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Generation of a silylene complex by the 1,2-migration of hydrogen from silicon to platinum

Angewandte Chemie - International Edition (1998) 37(18) 2524-2526
DOI: 10.1002/(SICI)1521-3773(19981002)37:18<2524::AID-ANIE2524>3.0.CO;2-H
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Abstract

An extraordinary downfield-shifted 29Si{1H} NMR signal is seen at δ = 338.5 for the platinum silylene complex [(dippe)(H)Pt=SiMes2][MeB(C6F5)3] (2). This remarkably stable metal silylene complex was obtained from 1 in the first intramolecular 1,2-hydride migration from silicon to a transition metal. dippe = iPr2PCH2CH2PiPr2, Mes = 2,4,6-Me3C6H2.

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Mitchell, G. P., & Tilley, T. D. (1998). Generation of a silylene complex by the 1,2-migration of hydrogen from silicon to platinum. Angewandte Chemie - International Edition, 37(18), 2524–2526. https://doi.org/10.1002/(SICI)1521-3773(19981002)37:18<2524::AID-ANIE2524>3.0.CO;2-H

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