Preparation of magnetic ion imprinted polymer with waste beer yeast as functional monomer for Cd(ii) adsorption and detection

Abstract

In this work, a magnetic ion imprinted polymer (MIIP) with specific recognition capability toward cadmium was prepared by a sol-gel method using waste beer yeast, which is a macromolecule biomass, as a functional monomer. The obtained Cd(ii)-MIIP was characterized using scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy and adsorption experiments. Then, a MIIP adsorbent based magnetic solid phase extraction (MSPE)-graphite furnace atomic absorption (GFAA) method was established to analyze the cadmium content in food and environmental samples. The maximum cadmium adsorption capacities by the MIIP and magnetic non-imprinted polymer (MNIP) were 62.74 and 32.38 mg g-1, respectively. The absorption by the MIIP was fitted using a pseudo-second-order kinetic model. The Cd(ii)-MIIP demonstrated superior absorption capability for selective removal cadmium. The recovery rate of the MIIP was 90.7% after four adsorption-desorption cycles. The calculated Cd(ii) detection limit (S/N = 3) was 0.18 μg L-1 with the relative standard deviation (RSD) equal to ∼3.5% for 10 μg L-1 of Cd(ii) standard solution. Our proposed method was successfully used in detecting Cd(ii) in aqueous samples. The results obtained in this work suggest that the Cd(ii)-MIIPs might be promising adsorbents to remove harmful cadmium ions from aqueous samples.