Kinetic Studies of the Reactions of Peroxy Compounds of Chromium (VI), Vanadium (V), and Titanium (IV) in Acid Media

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Abstract

The kinetics of formation and decomposition in perchloric and other acids of blue chromium(VI) diperoxy and the formation of red vanadium(V) monoperoxy, yellow vanadium(V) diperoxy, and orange titanium-(IV) monoperoxy species have been examined by flow methods. Rate laws have been established, and mechanisms are suggested for these reactions. © 1967, American Chemical Society. All rights reserved.

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Orhanović, M., & Wilkins, R. G. (1967). Kinetic Studies of the Reactions of Peroxy Compounds of Chromium (VI), Vanadium (V), and Titanium (IV) in Acid Media. Journal of the American Chemical Society, 89(2), 278–282. https://doi.org/10.1021/ja00978a019

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