A lvt-type framework [Cu2(tza)4]·ClO 4·4H2O derived from 1H-tetrazole-1-acetic acid

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Abstract

The reaction of 1H-tetrazole-1-acetic acid (Htza) and perchloric acid with cuprous chloride with slow evaporation at room temperature gave a novel 3D porous CuII coordination polymer, [Cu2(tza) 4]·ClO4·4H2O (1), (tza = tetrazole-1-acetate). The structure exhibits an unusual 3D microporous coordination framework built up by four coordinated CuII nodes and bidentate bridging tza ligands with lvt-type topology. Furthermore, the magnetic properties of complex 1 were also investigated. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Ma, L., Peng, G., Cai, J. B., Deng, H., & Zeller, M. (2011). A lvt-type framework [Cu2(tza)4]·ClO 4·4H2O derived from 1H-tetrazole-1-acetic acid. Zeitschrift Fur Anorganische Und Allgemeine Chemie, 637(6), 755–758. https://doi.org/10.1002/zaac.201000454

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