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Enantioselective Rhodium-Catalyzed Coupling of Arylboronic Acids, 1,3-Enynes, and Imines by Alkenyl-to-Allyl 1,4-Rhodium(I) Migration

Angewandte Chemie - International Edition (2017) 56(51) 16352-16356
DOI: 10.1002/anie.201709334
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Abstract

A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.

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Callingham, M., Partridge, B. M., Lewis, W., & Lam, H. W. (2017). Enantioselective Rhodium-Catalyzed Coupling of Arylboronic Acids, 1,3-Enynes, and Imines by Alkenyl-to-Allyl 1,4-Rhodium(I) Migration. Angewandte Chemie - International Edition, 56(51), 16352–16356. https://doi.org/10.1002/anie.201709334

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