Abstract
A novel semi-flexible Cd(II)-MOF has been synthesized and characterized by variable temperature powder and single-crystal X-ray diffraction. The material displays an unusual combination of thermal expansion (TE) i.e. negative, zero and positive, which is an extremely rare finding, especially for metal-organic frameworks as a result of a combined stretching-tilting mechanism. © The Partner Organisations 2014.
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CITATION STYLE
Lama, P., Kumar Das, R., Smith, V. J., & Barbour, L. J. (2014). A combined stretching-tilting mechanism produces negative, zero and positive linear thermal expansion in a semi-flexible Cd(II)-MOF. Chemical Communications, 50(49), 6464–6467. https://doi.org/10.1039/c4cc02634a
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