Morphology and crystal-plane effects of fe/w-ceo2 for selective catalytic reduction of no with nh3

Abstract

The CeO2 ordinary amorphous, nanopolyhedrons, nanorods, and nanocubes were prefabricated by the hydrothermal method, and employed as carriers of Fe/W-CeO2 catalysts to selectively catalyze the reduction of NO with ammonia. Characterization results indicated that the morphology of CeO2 support originated from selectively exposing different crystal surfaces, which has a significant effect on oxygen vacancies, acid sites and the dispersion of Fe2O3. The CeO2 nanopolyhedrons catalyst (Fe/W-CeO2-P) showed most oxygen vacancies, the largest the quantity of acid sites, the largest BET (Brunauer-Emmett-Teller) surface area and the best dispersion of Fe2O3, which was associated with predominately exposing CeO2 (111) planes. Consequently, the Fe/W-CeO2-P catalyst has the highest NO conversion rate in the temperature range of 100-325°C among the ordinary amorphous, nanorods, and nanocubes Fe/W-CeO2 catalysts.