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Synthesis and some stereoselective radical additions of bis[(phenyldimethylsilyl)methyl]tin dihydride

Arkivoc (2005) 2005(12) 88-97
DOI: 10.3998/ark.5550190.0006.c08
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Abstract

The synthesis of the new bis[(phenyldimethylsilyl)methyl]tin dihydride (6) starting from chloromethyldimethylsilicon chloride is reported. A study on the radical additions of 6 to various mono- and disubstituted alkynes shows that these reactions take place with high and in some cases with complete stereoselectivity. Full 1H-, 13C-, and 119Sn-NMR data of the new organtins are given. ©ARKAT.

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Faraoni, M. B., Dodero, V. I., & Podestá, J. C. (2005). Synthesis and some stereoselective radical additions of bis[(phenyldimethylsilyl)methyl]tin dihydride. Arkivoc, 2005(12), 88–97. https://doi.org/10.3998/ark.5550190.0006.c08

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