Development of an Adapted Water Quality Index for the Danube River Using Objective Weighting Methods

Abstract

The Danube River is one of Europe’s largest transboundary rivers, characterized by substantial spatial heterogeneity in environmental conditions, monitoring practices, and water management frameworks. Developing a harmonized approach for basin-wide surface-water quality assessment is therefore essential. This study presents the development and application of an adapted Water Quality Index (Danube WQI) for assessing and monitoring water quality along the Danube River, one of Europe’s largest and most complex transboundary systems. The Danube WQI is based on established WQI methodologies and integrates two objective weighting approaches—the Entropy Weight Method (EWM) and the CRITIC (Criteria Importance Through Inter-Criteria Correlation) method—to minimize subjectivity and improve the robustness of parameter weighting. Long-term water quality data from the TransNational Monitoring Network (TNMN) of the International Commission for the Protection of the Danube River (ICPDR) were used, covering 42 stations across nine countries (1996–2022). Nine parameters were selected: dissolved oxygen (DO), biochemical oxygen demand (BOD5), total nitrogen (TN), nitrate (NO3), ammonium (NH4), total phosphorus (TP), orthophosphate (PO4), electrical conductivity (EC), and pH. During the formation of sub-indices and rating curves, national water quality standards from the Danube countries were harmonized to ensure consistent parameter classification. Results indicate that the Danube River generally exhibits very good water quality, with most sections belonging to the first and second quality classes. Comparison with the Canadian Water Quality Index (CWQI) confirmed similar results but demonstrated higher seasonal sensitivity of the Danube WQI. Additionally, rankings obtained using the PROMETHEE II multicriteria method showed strong agreement with the Danube WQI classifications, further confirming the robustness of the proposed index. The proposed index provides a harmonized and transferable framework that can support integrated water management and policy evaluation across the Danube River Basin and within the EU Water Framework Directive context.