The experimental realization of a neutral homoaromatic carbocycle

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Abstract

Infrared spectra recorded for 1,5-dimethyl-2,8:4,6- semibullvalenetetracarboxylic acid dianhydride (12) in the condensed and vapor phase clearly prove that in the vapor phase the dianhydride 12 is a homoaromatic ground state semibullvalene. The bisannelated semibullvalene depicted is demonstrated to be a ground-state-neutral homoaromatic carbocycle through vapor-phase infrared spectroscopy. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Griffiths, P. R., Pivonka, D. E., & Williams, R. V. (2011). The experimental realization of a neutral homoaromatic carbocycle. Chemistry - A European Journal, 17(33), 9193–9199. https://doi.org/10.1002/chem.201100025

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