Abstract
We introduce here a new subclass of copper(i) hybrid emitters simultaneously containing [CuxIy]z− anions and Cu+ cations, separated in space by a Janus head ligand. When UV-irradiated at 298 K, these unique “Two-In-One” hybrids exhibit a short-lived green TADF with near-unity quantum yield and a strong solvatochromic effect. Moreover, they manifest a strong radioluminescence upon X-ray irradiation. These findings open up new possibilities for the design of highly performing TADF materials.
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CITATION STYLE
Baranov, A. Y., Rakhmanova, M. I., Hei, X., Samsonenko, D. G., Stass, D. V., Bagryanskaya, I. Y., … Artem’ev, A. V. (2023). A new subclass of copper(i) hybrid emitters showing TADF with near-unity quantum yields and a strong solvatochromic effect. Chemical Communications, 59(20), 2923–2926. https://doi.org/10.1039/d3cc00119a
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