Tetrakis(arylisocyanide) rhodium(I) salts in water: NIR luminescent and conductive supramolecular polymeric nanowires with hierarchical organization

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Abstract

Fish out of water: Amphiphilic tetrakis(2,6-xylylisocyanide)rhodium(I) complexes can self-assemble in water, through RhI RhI and hydrophobic interactions, into ultralong crystalline nanowires and in turn hierarchically organize into a variety of ordered micro- and macrostructures. These solution-processable organometallic superstructures are luminescent in the near-infrared (NIR) region and are electrically conducting. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Chen, Y., Li, K., Lloyd, H. O., Lu, W., Chui, S. S. Y., & Che, C. M. (2010). Tetrakis(arylisocyanide) rhodium(I) salts in water: NIR luminescent and conductive supramolecular polymeric nanowires with hierarchical organization. Angewandte Chemie - International Edition, 49(51), 9968–9971. https://doi.org/10.1002/anie.201005223

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