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π-Lewis Base Activation of Carbonyls and Hexafluorobenzene

Angewandte Chemie - International Edition (2025) 64(6)
DOI: 10.1002/anie.202418738
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Abstract

We report hitherto elusive side-on η2-bonded palladium(0) carbonyl (anthraquinone, benzaldehyde) and arene (benzene, hexafluorobenzene) palladium(0) complexes and present the catalytic hydrodefluorination of hexafluorobenzene by cyclohexene. The comparison with respective cyclohexene, pyridine and tetrahydrofuran complexes reveals that the experimental ligand binding strengths follow the order THF

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Mondal, A., Breitwieser, K., Danés, S., Grünwald, A., Heinemann, F. W., Morgenstern, B., … Munz, D. (2025). π-Lewis Base Activation of Carbonyls and Hexafluorobenzene. Angewandte Chemie - International Edition, 64(6). https://doi.org/10.1002/anie.202418738

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