Direct allylation of quinones with allylboronates

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Abstract

Allylboronates undergo C-H allylation of unsubstituted or monosubstituted benzoquinone and naphthoquinone substrates. In the case of 2,5-or 2,6-disubstituted quinones addition involving the substituted carbon takes place. Allylation with stereodefined allylboronates occurs with retention of the configuration.

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Deng, H. P., Wang, D., & Szabó, K. J. (2015). Direct allylation of quinones with allylboronates. Journal of Organic Chemistry, 80(6), 3343–3348. https://doi.org/10.1021/acs.joc.5b00264

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