Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: Reductive silylation

25Citations
Citations of this article
9Readers
Mendeley users who have this article in their library.

Abstract

1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene is an effective silyl transfer reagent towards the oxygen of nitrate coordinated to Cr(iii) in a pincer complex. Two nitrate oxygens are removed to give the 17 valence electron octahedral complex (H2L)Cr(NO3)2(NO). This is shown by a variety of spectroscopic methods, together with DFT, to be a Cr(i) complex with a linear CrNO unit. This work also identifies future applications of this reductive silylation process.

Cite

CITATION STYLE

APA

Seo, J., Cabelof, A. C., Chen, C. H., & Caulton, K. G. (2019). Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: Reductive silylation. Chemical Science, 10(2), 475–479. https://doi.org/10.1039/c8sc02979b

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free