Especiação e quimissorção de Pb(II) em rejeito de caulim

Abstract

This study assesses the adsorption of Pb(II) on natural kaolin waste (KRnatural) and on that treated with 3 mol L-1 H2SO 4 and HCl. Equilibrium and thermodynamic parameters were determined. The results indicate that the values of CEC, specific area and SiO 2/Al2O3 ratio (4.6-6.0 cmol kg-1, 14.0-16.0 m2 g-1 and 1.16-1.30, respectively) vary only slightly for the adsorbents; the concentration of Pb2+ is much higher than that of other species (PbOH+ and Pb(OH)2). The values of RL, ΔGo, ΔHo and ΔSo are typical of feasible, spontaneous, exothermic and ordered adsorption. The chemisorption on KRnatural is more feasible and ordered.