Push-pull 1,4-dithiafulvenes: A combined experimental and theoretical study

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Abstract

Novel push-pull 6,6-disubstituted 1,4-dithiafulvenes have been synthesized and their electrochemical and spectral properties were recorded. The proaromaticity of the donor end of these alkenes lies at the origin of their strong dipolar character, confirmed by DFT calculations, and their second-order NLO properties.

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Andreu, R., Cerdán, M. A., Garín, J., & Orduna, J. (2004). Push-pull 1,4-dithiafulvenes: A combined experimental and theoretical study. Arkivoc, 2004(4), 32–41. https://doi.org/10.3998/ark.5550190.0005.405

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