Abstract
Trisubstituted olefins are reactants in template-directed, solid-state [2+2] photocycloaddition reactions. Whereas hydrogen-bond-based templates afford crystalline assemblies with olefins that are photostable, AgI coordination results in carbon–carbon double bonds that react stereoselectively and result in quantitative yield.
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Elacqua, E., Sinnwell, M. A., Loren, B. P., Jurgens, P. T., Groeneman, R. H., Reinheimer, E. W., & MacGillivray, L. R. (2016). Metal–Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State. ChemPlusChem, 81(8), 893–898. https://doi.org/10.1002/cplu.201600261
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