Hydrogenation of Carbon Dioxide to Value-Added Liquid Fuels and Aromatics over Fe-Based Catalysts Based on the Fischer–Tropsch Synthesis Route

Abstract

Hydrogenation of CO2 to value-added chemicals and fuels not only effectively alleviates climate change but also reduces over-dependence on fossil fuels. Therefore, much attention has been paid to the chemical conversion of CO2 to value-added products, such as liquid fuels and aromatics. Recently, efficient catalysts have been developed to face the challenge of the chemical inertness of CO2 and the difficulty of C–C coupling. Considering the lack of a detailed summary on hydrogenation of CO2 to liquid fuels and aromatics via the Fischer–Tropsch synthesis (FTS) route, we conducted a comprehensive and systematic review of the research progress on the development of efficient catalysts for hydrogenation of CO2 to liquid fuels and aromatics. In this work, we summarized the factors influencing the catalytic activity and stability of various catalysts, the strategies for optimizing catalytic performance and product distribution, the effects of reaction conditions on catalytic performance, and possible reaction mechanisms for CO2 hydrogenation via the FTS route. Furthermore, we also provided an overview of the challenges and opportunities for future research associated with hydrogenation of CO2 to liquid fuels and aromatics.