On the nature of chemical bonding in γ-boron

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Abstract

The chemical bonding in γ-boron has been discussed, based on the known crystal structures of the new recently discovered phase. The unexpected polarity of some B-B bonds and a sensible electron counting scheme are presented. The relationship between the chemical bonding and the material hardness is also discussed. © Allerton Press, Inc., 2011.

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Macchi, P. (2011). On the nature of chemical bonding in γ-boron. Journal of Superhard Materials, 33(6), 380–387. https://doi.org/10.3103/S1063457612060020

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