Water stable colloidal PVP coated spin crossover nanoparticles

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Abstract

Stable aqueous dispersions of spin-crossover (SCO) doped [FeII(Htrz)2(trz)](BF4) nanoparticles (NPs) were prepared by using water-soluble polyvinylpyrrolidone (PVP) as protecting polymer. The metal or ligand substitution percentage regulated the ultra-small size and morphology of the NPs. At the same time, the colloidal dispersions showed a complete conversion of the LS state to the HS state of the FeII ion.

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Polyzou, C. D., Zygouri, E., Lalioti, N., Malina, O., Polaskova, M., Bednar, J., & Tangoulis, V. (2024). Water stable colloidal PVP coated spin crossover nanoparticles. Dalton Transactions, 53(41), 16821–16825. https://doi.org/10.1039/d4dt02670e

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