The first total synthesis of the neuroactive indole alkaloid (±)-alstoscholarisine A is reported. The key step of the concise synthesis is an efficient domino sequence that was used to assemble the 2,8-diazabicyclo[3.3.1]nonane core through the formation of two C-N bonds and one C-C bond in a single step. A change of mind: The first total synthesis of the neuroactive indole alkaloid (±)-alstoscholarisine A is reported. The key step of the concise synthesis is an efficient domino sequence that was used to assemble the 2,8-diazabicyclo[3.3.1]nonane core through the formation of two C-N bonds and one C-C bond in a single step.
CITATION STYLE
Bihelovic, F., & Ferjancic, Z. (2016). Total Synthesis of (±)-Alstoscholarisine A. Angewandte Chemie - International Edition, 55(7), 2569–2572. https://doi.org/10.1002/anie.201510777
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