Morphology and properties of nylon 6 blown films reinforced with different weight percentage of nanoclay additives

Abstract

This article presents the effect of increasing weight percentage natural nanoclay additives on the structure, morphology and mechanical properties of nylon-6-blown films. Combination of X-ray diffraction, thermal analysis and microscopy were used to determine nanocomposite film morphology. The nanoclay additives in the films act as nucleating agent facilitates γ-crystalline forms and results in fine grained spherulite with smaller lamellar size. Increase in tensile, burst, and tear strength is observed for films with up to 5% clay loading. Even though microscale property like tensile and tear strength drops at higher add on levels, near-surface nanoscale hardness and toughness of the film keep on increasing. There is a direct correlation between nanoclay additive add on level and increase in surface energy and wetting behavior of films. © 2012 Raghavendra R. Hegde et al.