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Transition from Low to High Iodide and Iodine Concentration States in the Briggs-Rauscher Reaction: Evidence on Crazy Clock Behavior

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Abstract

The Briggs-Rauscher reaction containing malonic acid may undergo a sudden transition from low (state I) to high iodide and iodine (state II) concentration states after a well-defined and strongly reproducible oscillatory period. This study clearly shows that even though the time-dependent behavior of the oscillatory state is reproducible, the time lag necessary for the appearance of the state I to state II transition after the system leaves the oscillatory state becomes irreproducible for an individual kinetic run. This crazy clock behavior of the state I to state II transition is identified by repeated experiments in which stirring rate is taken as a control parameter and all other parameters such as initial conditions, temperature, vessel surface, and the age of solution were kept constant. Surprisingly, a better stirring condition does not make the transition reproducible; it simply does not allow the transition to happen at all. The proposed mechanism, additional explanations, and proposals for this irreproducibility of state I to state II transition have been presented. Considering the fact that the number of crazy clock reactions is only a few, this study may contribute to a better understanding of fundaments of this phenomenon.

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APA

Pagnacco, M. C., Maksimović, J. P., Potkonjak, N. I., Božić, B. D., & Horváth, A. K. (2018). Transition from Low to High Iodide and Iodine Concentration States in the Briggs-Rauscher Reaction: Evidence on Crazy Clock Behavior. Journal of Physical Chemistry A, 122(2), 482–491. https://doi.org/10.1021/acs.jpca.7b11774

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