Enantioselective conjugate hydrosilylation of α,β-unsaturated ketones

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Abstract

Enantioselective conjugate hydrosilylation of β,β-disubstituted α,β-unsaturated ketones was realized. In the presence of a chiral picolinamide-sulfonate Lewis base catalyst, the reactions provided various chiral ketones bearing a chiral center at the β-position in up to quantitative yields with moderate enantioselectivities.

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Yang, H., Weng, G., Fang, D., Peng, C., Zhang, Y., Zhang, X., & Wang, Z. (2019). Enantioselective conjugate hydrosilylation of α,β-unsaturated ketones. RSC Advances, 9(21), 11627–11633. https://doi.org/10.1039/c9ra01180c

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