Abstract
Substituted indenes can be prepared after a sequence [1,3] O-acyl shift-hydroarylation-[1,3] O-acyl shift. Each step is catalyzed by a cationic NHC-Gold(i) species generated in situ after reaction between [(IPr)AuOH] and HBF4·OEt2. This interesting silver-free way is fully supported by a computational study justifying the formation of each intermediate. © 2011 The Royal Society of Chemistry.
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APA
Nun, P., Gaillard, S., Poater, A., Cavallo, L., & Nolan, S. P. (2011). A combined mechanistic and computational study of the gold(I)-catalyzed formation of substituted indenes. Organic and Biomolecular Chemistry, 9(1), 101–104. https://doi.org/10.1039/c0ob00758g
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