Optimal ranges of variables for an effective adsorption of lead(II) by the agricultural waste pomelo (Citrus grandis) peels using Doehlert designs

Abstract

The capacity of pomelo peels' adsorption on lead(II) from aqueous solutions without modifications was investigated and confirmed. Four variables in this study, pH, temperature, time and initial concentration of lead(II), significantly affected the adsorption rate of pomelo peels. The prediction model and optimal ranges of optimized variables were given by Doehlert designs, which made the selection of variables rapid, flexible and effortless to obtain an adsorption rate reaching 99.9% and 20 mg/L for initial lead(II) concentration, 3 for pH, 50 °C for temperature and 210 min for time was a choice. The higher correlation coefficient as well as the more consistent value of experimental equilibrium adsorption capacity of the pseudo-first-order model suggested it bore a better prediction of the adsorption kinetics than the pseudo-second-order model. Langmuir model indicated the adsorption mechanism of pomelo peels was monolayer sorption with the help of both physical adsorption and chemical bonding, which were demonstrated by scanning electron microscopy and Fourier transform-infrared, respectively. The ability of pomelo peels to adsorb lead(II) from aqueous solutions was not interfered with the presence of calcium(II), magnesium(II), copper(II) and zinc(II). Pomelo peels had the potential to be utilized in the simultaneous adsorption of toxic heavy metal ions.