Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-: I h

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Abstract

The Dy-Sc nitride clusterfullerene Dy2ScN@C80-Ih exhibits slow relaxation of magnetization up to 76 K. Above 60 K, thermally-activated relaxation proceeds via the fifth-excited Kramers doublet with the energy of 1735 ± 21 K, which is the highest barrier ever reported for dinuclear lanthanide single molecule magnets.

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Krylov, D. S., Liu, F., Avdoshenko, S. M., Spree, L., Weise, B., Waske, A., … Popov, A. A. (2017). Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy2ScN@C80-: I h. Chemical Communications, 53(56), 7901–7904. https://doi.org/10.1039/c7cc03580b

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