Synthesis of 3D Cadmium(II)-Carboxylate Framework Having Potential for Co-Catalyst Free CO2 Fixation to Cyclic Carbonates

Abstract

Metal-organic frameworks (MOFs) are porous coordination polymers with interesting structural frameworks, properties, and a wide range of applications. A novel 3D cadmium(II)-carboxylate framework, CdMOF ([Cd2(L)(DMF)(H2O)2]n), was synthesized by the solvothermal method using a tetracarboxylic bridging linker having amide functional moieties. The CdMOF crystal structure exists in the form of a 3D layer structure. Based on the single-crystal X-ray diffraction studies, the supramolecular assembly of CdMOF is explored by Hirshfeld surface analysis. The voids and cavities analysis is performed to check the strength of the crystal packing in CdMOF. The CdMOF followed a multistage thermal degradation pattern in which the solvent molecules escaped around 200 °C and the structural framework remained stable till 230 °C. The main structural framework collapsed (>60 wt.%) into organic volatiles between 400–550 °C. The SEM morphology analyses revealed uniform wedge-shaped rectangular blocks with dimensions of 25–100 μm. The catalytic activity of CdMOF for the solvent and cocatalyst-free cycloaddition of CO2 into epichlorohydrin was successful with 100% selectivity. The current results revealed that this 3D CdMOF is more active than the previously reported CdMOFs and, more interestingly, without using a co-catalyst. The catalyst was easily recovered and reused, having the same performance.