Covalently linked [60,70] fullerenes-nitroxide unit for synthesis and characterization

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Abstract

Based on the conditions for the formation of stable nitroxides, that is, oxidation of a secondary amine which has no α-H, 2-aminoisobutyric acid and diketone were used to react with C60 via 1,3-dipolar cycloaddition to yield [60]fulleropyrrolidine. It is proposed that the compound of bis-fulleropyrrolidines 1 can be synthesized. Furthermore, the bis-fulleropyrrolidines can be oxidized to give a stable bis-nitroxide based on fullerene. However, the results have pointed out that the reactions with C60 only afforded monoadducts 2a after decarboxylation and dehydration perhaps due to steric hindrance.

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Shi, Z., Li, Y., Xu, J., Ge, Z., & Zhu, D. (2000). Covalently linked [60,70] fullerenes-nitroxide unit for synthesis and characterization. Journal of Physics and Chemistry of Solids, 61(7), 1095–1099. https://doi.org/10.1016/S0022-3697(99)00367-4

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