Yntheses of pseudo-α-D-glucopyranose and pseudo-β-l-idopyranose, two optically active pseudo-hexopyranoses, from d-glucose by using stereoselective reductive deacetoxylation with sodium borohydride and cyclitol formation from nitrofuranose as key reactions

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Abstract

Two optically active pseudo-hexopyranoses, pseudo-a-D-glucopyranose and pseudo-3-L-idopyranose, have been synthesized from D-glucose by using stereoselective deacetoxylations with NaBH^ and cyclitol formations from nitrofuranose derivatives as key reactions. © 1988, The Pharmaceutical Society of Japan. All rights reserved.

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Yoshikawa, M., Cha, B. C., Nakae, T., & Kitagawa, I. (1988). Yntheses of pseudo-α-D-glucopyranose and pseudo-β-l-idopyranose, two optically active pseudo-hexopyranoses, from d-glucose by using stereoselective reductive deacetoxylation with sodium borohydride and cyclitol formation from nitrofuranose as key reactions. Chemical and Pharmaceutical Bulletin, 36(9), 3714–3717. https://doi.org/10.1248/cpb.36.3714

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