Skeletal change in the PNP pincer ligand leads to a highly regioselective alkyne dimerization catalyst

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Abstract

A Rh complex of a bulky diarylamino-based PNP pincer ligand is a robust catalyst for the dimerization of terminal alkynes and highly selective for the trans-enyne product. © The Royal Society of Chemistry 2006.

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Weng, W., Guo, C., Çelenligil-Çetin, R., Foxman, B. M., & Ozerov, O. V. (2006). Skeletal change in the PNP pincer ligand leads to a highly regioselective alkyne dimerization catalyst. Chemical Communications, (2), 197–199. https://doi.org/10.1039/b511148j

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