Arsenate removal from aqueous solution using chitosan-coated bentonite, chitosan-coated kaolinite and chitosan-coated sand: Parametric, isotherm and thermodynamic studies

Abstract

In the present work, the removal efficiency of As(V) from aqueous solution using chitosan-coated bentonite (CCB), chitosan-coated kaolinite (CCK) and chitosan-coated sand (CCS) was evaluated. The chitosan-based adsorbents were characterized using scanning electron microscopy, Fourier-transform infrared spectroscopy, the Brunauer-Emmett-Teller method and thermogravimetric analysis. Kinetic studies revealed that As(V) uptake using CCB, CCK and CCS fitted well with the pseudo-second order equation (R2 0.9847; RMSE 9.1833). Equilibrium data show good correlation with the Langmuir model (R2 0.9753; RMSE 8.5123; SSE 16.2651) for all adsorbents, which implies monolayer coverage onto homogenous energy sites. The Langmuir adsorption capacity for As (V) at pH 7.0 was determined to be 67.11, 64.85, and 16.78 mg/g for CCB, CCK and CCS, respectively. Thermodynamic studies show that As(V) uptake is exothermic in nature using CCK and endothermic using CCB and CCS. Moreover, adsorption of As(V) was feasible and spontaneous for CCB and CCS at 298 to 328 K. Results show that CCB is the most effective adsorbent in the removal of As(V) from water due to its high surface area and large pore diameter.