Carboxymethylation of Organic Halides by Palladium Complexes under Mild Conditions

  • Hidai M
  • Hikita T
  • Wada Y
  • et al.
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Abstract

Palladium complexes, Pd(CO)(PPh3)3, Pd3(CO)3(PPh3)4, Pd3(CO)3(PPh3)3, and PdCl2(PPh3)2 were found to be excellent catalysts for the carboxymethylation of various organic halides under very mild conditions. The carboxymethylation reaction is considered to proceed via acyl complexes as the intermediates.

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Hidai, M., Hikita, T., Wada, Y., Fujikura, Y., & Uchida, Y. (1975). Carboxymethylation of Organic Halides by Palladium Complexes under Mild Conditions. Bulletin of the Chemical Society of Japan, 48(7), 2075–2077. https://doi.org/10.1246/bcsj.48.2075

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