Surface Modification of Fe-Based Perovskite Oxide via Sr0.95Ce0.05CoO3−δ Infiltration: A Strategy for Thermochemical Stability

Abstract

Cobalt-based perovskite oxides exhibit remarkable catalytic activity owing to abundant oxygen vacancies and mixed ionic–electronic conductivity, but they suffer from structural instability. In contrast, iron-based perovskite oxides are thermochemically stable under oxidizing and reducing conditions but are catalytically limited. To combine these complementary properties, a composite perovskite oxide was designed and prepared by infiltrating Sr0.95Ce0.05CoO3−δ (SCC) into Ba0.5Sr0.5Fe0.8Cu0.2O3−δ (BSFC). The SCC precursor solution was dropwise applied to a BSFC|SDC|BSFC symmetric cell and heat treated. Surface morphology and compositional analyses confirmed the distribution of SCC nanoparticles on the BSFC surface. High-temperature X-ray diffraction and Rietveld refinement results revealed that both BSFC and SCC retained the cubic perovskite structure (space group Pm-3m) at room temperature. No phase transition or secondary phase formation was observed during heating from 200 to 800 °C, and the peak shifts are attributed to thermal expansion and possible oxygen loss at elevated temperatures. Upon cooling, the diffraction patterns returned to their initial state, confirming a high-temperature structural stability. XPS analysis showed an increase in the satellite peak intensity associated with Fe3+ after SCC infiltration, and the average oxidation state of Fe decreased from 3.52 (BSFC) to 3.49 (composite perovskite oxide). The O 1s spectra revealed a higher relative content of surface-adsorbed oxygen species in the composite, indicating increased oxygen vacancy formation.