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Reaction of Aldonitrones with N-Phenyl-9,10-dihydro-9,10-ethenoanthracene-11,12-dicarboximide

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Abstract

Thermal addition of aldonitrones (C,N-diaryl- and N-aryl-C-arylcarbamoylnitrones) to the double bond of N-phenyl-9,10-dihydro-9,10-ethenoanthracene-11,12-dicarboximide yields heteropropellanes containing isoxazolidine and pyrrolidine fragments. The cycloaddition of C,N-diarylnitrones is stereoselective, and only one diastereoisomer is formed.

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Molchanov, A. P., Efremova, M. M., Stepakov, A. V., Panikorovskii, T. L., & Kostikov, R. R. (2018). Reaction of Aldonitrones with N-Phenyl-9,10-dihydro-9,10-ethenoanthracene-11,12-dicarboximide. Russian Journal of Organic Chemistry, 54(3), 463–468. https://doi.org/10.1134/S1070428018030144

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