Investigation of the rotational spectrum of CH317OH and its tentative detection toward Sagittarius B2(N)

Abstract

Context. Methanol is an abundant and widespread molecule in the interstellar medium. The column density of its 18O isotopolog, CH3 18OH, is in some star-forming regions so high that the search for CH3 17OH is promising. But only very few transition frequencies of CH3 17OH with a microwave accuracy have been published prior to our investigation. Aims. We want to extend the very limited rotational line list of CH3 17OH to be able to search for this isotopolog in the interstellar medium. Methods. We recorded the rotational spectrum of CH3 17OH between 38 and 1095 GHz employing a methanol sample enriched in 17O to 20%. A torsion-rotation Hamiltonian model based on the rho-axis method was employed to fit the data, as in our previous studies. We searched for rotational transitions of CH3 17OH in the imaging spectral line survey ReMoCA obtained with the Atacama Large Millimeter/submillimeter Array (ALMA) toward the high-mass star-forming region Sgr B2(N). The observed spectra were modeled under the assumption of local thermodynamic equilibrium (LTE). Results. The assignments cover 0 = J = 45, Ka = 16, and mainly the 3t = 0 and 1 torsional states. The Hamiltonian model describes our data well. The model was applied to derive a line list for radio-astronomical observations. We report a tentative detection of CH3 17OH along with secure detections of the more abundant isotopologs of methanol toward Sgr B2(N2b). The derived column densities yield isotopic ratios 12C/13C = 25, 16O/18O = 240, and 18O/17O = 3.3, which are consistent with values found earlier for other molecules in Sgr B2. Conclusions. The agreement between the 18O/17O isotopic ratio that we obtained for methanol and the 18O/17O ratios reported in the past for other molecules in Sgr B2(N) strongly supports our tentative interstellar identification of CH3 17OH. The accuracy of the derived line list is sufficient for further radio astronomical searches for this methanol isotopolog toward other star-forming regions. The Authors 2024.