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Abstract

Dissociation enthalpies of terminal (N–O) bonds, DH(N–O), in amine N-oxides, nitrile N-oxides, pyridine N-oxides, quinoxaline 1,4-dioxides, furoxans, nitrones, azoxy- derivatives, azo-N,N-dioxides, nitro compounds, nitramines, and alkyl nitrates are calcu- lated from published enthalpy of formation, enthalpy of sublimation, and enthalpy of vaporization data. For each class of organic compounds, the calculated DH(N–O) val- ues are critically evaluated. The derived DH(N–O) values can be used to estimate enthalpies of formation of other molecules in each of these classes of organic compounds.

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Acree, W. E., Pilcher, G., & Ribeiro Da Silva, M. D. M. C. (2005). The dissociation enthalpies of terminal (N-O) bonds in organic compounds. Journal of Physical and Chemical Reference Data, 34(2), 553–572. https://doi.org/10.1063/1.1851531

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