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Highly cis-selective and lead-free hydrogenation of 2-hexyne by a supported Pd catalyst with an ionic-liquid layer

Chemical Communications (2014) 50(72) 10406-10408
DOI: 10.1039/c4cc04183f
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Abstract

A simple Pd/SiO2 catalyst which was modified with the ionic liquid [BMPL][DCA] gave an excellent yield of 88% towards cis-2-hexene in the stereoselective hydrogenation of 2-hexyne. The catalyst outperforms, even at full conversion, the commonly used lead-poisoned, toxic Lindlar catalyst and supported colloidal-based Pd as well. © 2014 The Royal Society of Chemistry.

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APA

Schwab, F., Weidler, N., Lucas, M., & Claus, P. (2014). Highly cis-selective and lead-free hydrogenation of 2-hexyne by a supported Pd catalyst with an ionic-liquid layer. Chemical Communications, 50(72), 10406–10408. https://doi.org/10.1039/c4cc04183f

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