Calix[4]arene derivatives of titanium and zirconium alkoxides

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Abstract

Reaction of Ti(OBu)4 or Zr(OBu)4 with tbutyl-calix[4]arene, calyxtBu(OH)4, led to the formation of Ti2(OBu)2 [calixtBuO3 (OH)] 2 and Zr3 (OBu) 8 (calixtBuO4), respectively. Upon in situ generation of water in the reaction with Zr(OBu) 4, the partially hydrolyzed compound Zr4O(OBu) 6 (calixtBuO4)2 (BuOH) 2 was isolated.

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Czakler, M., Artner, C., Maurer, C., & Schubert, U. (2014). Calix[4]arene derivatives of titanium and zirconium alkoxides. Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences, 69(11–12), 1253–1259. https://doi.org/10.5560/ZNB.2014-4121

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