Consistency evaluation of tropospheric ozone from ozonesonde and IAGOS (In-service Aircraft for a Global Observing System) observations: vertical distribution, ozonesonde types, and station-airport distance

Abstract

The vertical distribution of tropospheric O3 from ozonesondes is compared with that from In-service Aircraft for a Global Observing System (IAGOS) measurements collected at 23 pairs of sites between about 30° S and 55° N from 1995 to 2021. Profiles of tropospheric O3 from IAGOS are generally in good agreement with ozonesonde observations from electrochemical concentration cells (ECCs), Brewer-Mast sondes, and carbon-iodine sensors, with average biases of 2.58, -0.28, and 0.67 ppb and correlation coefficients (R) of 0.72, 0.82, and 0.66, respectively. Agreement between aircraft and Indian-sonde observations is poor, with an average bias of 15.32 ppb and an R value of 0.44. The O3 concentration observed by ECC sondes is, on average, 5 %-10 % higher than that observed by IAGOS, and the relative bias increases modestly with altitude. For other sonde types, there are some seasonal and altitudinal variations in the relative bias with respect to the IAGOS measurements, but these appear to be caused by local differences. The distance between the station and airport, when within 4° (latitude and longitude), has little effect on the comparison results. For the ECC ozonesondes, the overall bias with respect to the IAGOS measurements varies from 5.7 to 9.8 ppb when the station pairs are grouped by station-airport distances of <1° (latitude and longitude), 1-2°, and 2-4°. Correlations for these groups correspond to RCombining double low line0.8, 0.9, and 0.7. These comparison results provide important information for merging ozonesonde and IAGOS measurement datasets. They can also be used to evaluate the relative biases of different sonde types in the troposphere, using the aircraft as a transfer standard.