New solid solution and phase equilibria in the subsolidus area of the three-component CuO–V2O5–Ta2O5 oxide system

Abstract

The results of the study of the three-component system of CuO–V2O5–Ta2O5 oxides showed, inter alia, that in the air atmosphere in one of its cross-sections, i.e., in the CuV2O6–CuTa2O6 system, a new substitutional solid solution with the general formula CuTa2−xVxO6 and homogeneity range for x > 0.0 and x ≤ 0.3 is formed. The influence of the degree of incorporation of V5+ ions into the CuTa2O6 crystal lattice in place of Ta5+ ions on the unit cell volume, thermal stability and IR spectra of the obtained solid solution was determined. Moreover, the value of the band gap energy of the CuTa2−xVxO6 solid solution was estimated in the range of 0.0 < x ≤ 0.3, and on this basis, the new solid solution was classified as a semiconductor. On the basis of the research results, the studied system of CuO–V2O5–Ta2O5 oxides was also divided into 12 subsidiary subsystems.