Diels-Alder reactions of beta-vinyl-meso-tetraphenylporphyrin with quinones

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Abstract

Ni(II)-2-vinyl-5,10,15,20-tetraphenylporphyrin reacts with 1,4-naphthoquinone and 1,4-benzoquinone to afford mixtures of rigid porphyrin-quinone derivatives with extended π-systems. The structures of these novel compounds were deduced from detailed NMR experiments. ©ARKAT.

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Faustino, M. A. F., Neves, M. G. P. M. S., Tomé, A. C., Silva, A. M. S., & Cavaleiro, J. A. S. (2005). Diels-Alder reactions of beta-vinyl-meso-tetraphenylporphyrin with quinones. Arkivoc, 2005(9), 332–343. https://doi.org/10.3998/ark.5550190.0006.928

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