Bis(6-meth-oxy-2-{[tris-(hydroxy-meth-yl)-meth-yl]-imino-meth-yl}phenolato) -copper(II) dihydrate

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Abstract

In the title compound, [Cu(C12H16NO5)2]·2H2O, the CuII ion adopts a trans-CuN2O4 octa-hedral geometry arising from two N,O,O′-tridentate 6-meth-oxy-2-{[tris-(hydroxy-meth-yl)meth-yl]-imino- meth-yl}phenolate ligands. The Jahn-Teller distortion of the copper centre is unusally small. In the crystal structure, O - H⋯O hydrogen bonds, some of which are bifurcated, link the component species.

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Zhang, X., Wei, P., Dou, J., Li, B., & Hu, B. (2009). Bis(6-meth-oxy-2-{[tris-(hydroxy-meth-yl)-meth-yl]-imino-meth-yl}phenolato) -copper(II) dihydrate. Acta Crystallographica Section E: Structure Reports Online. International Union of Crystallography. https://doi.org/10.1107/S1600536808043948

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