3-(4-Chloro-phen-yl)-4-(4-methoxyphen-yl)-6-(phenyl-selenylmeth-yl)-2,3,3a, 3b,4,5,5a,6,1′′,2′′,3′′,4′′-do- deca-hydro-azeto[2′,3′:3,4]pyrrolo[1,2-b]isoxazole-2-spiro- 2′′-naphthalene-5,1′′-dione

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Abstract

In the title compound, C36H31ClN2O4Se, the four-membered Β-lactam ring is fused to a pyrrolidine ring. The central five-membered ring of the fused tricyclic system exhibits an envelope conformation with the N atom as the flap, while the other five-membered ring exhibits a twist conformation. The chloro-phenyl ring is almost perpendicular to the pyrrolidine ring, making a dihedral angle of 73.45 (1)°. The crystal structure is stabilized by weak inter-molecular C - H⋯O inter-actions and the packing is further enhanced by C - H ⋯N inter-actions and π-π inter-actions between benzene rings of tetra-lone groups in mol-ecules related by an inversion center, with a centroid-centroid separation of 3.8923 (2) Å.

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Kamala, E. T. S., Nirmala, S., Sudha, L., Arumugam, N., & Raghunathan, R. (2008). 3-(4-Chloro-phen-yl)-4-(4-methoxyphen-yl)-6-(phenyl-selenylmeth-yl)-2,3,3a, 3b,4,5,5a,6,1′′,2′′,3′′,4′′-do- deca-hydro-azeto[2′,3′:3,4]pyrrolo[1,2-b]isoxazole-2-spiro- 2′′-naphthalene-5,1′′-dione. Acta Crystallographica Section E: Structure Reports Online, 64(4). https://doi.org/10.1107/S1600536808006570

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