The behavior of melts with vanishing viscosity in the cone-and-plate rheometer

Abstract

A semi-analytic solution for material flow in the cone-and-plate rheometer is presented. It is assumed that the viscosity is solely a function of the second invariant of the strain rate tensor. A distinguishing feature of the constitutive equations used is that the viscosity is vanishing as the shear strain rate approaches infinity. This feature of the constitutive equations affects the qualitative behavior of the solution. Asymptotic analysis is carried out near the surface of the cone to reveal these features. It is shown that the regime of sliding must occur and the shear strain rate approaches infinity under certain conditions. It is also shown that the asymptotic behavior of the viscosity as the shear strain rate approaches infinity controls these qualitative features of the theoretical solution. Some of these features are feasible for experimental verification. An interpretation of the theoretical solution found is proposed.