1,1′-(Ethane-1,2-diyl)dipyridinium dichromate(VI)

Abstract

In the cation of the title salt, (C 12H 14N 2)[Cr 2O 7], the two pyridinium moieties are in an anti orientation with respect to one another. The dihedral angle between the pyridine rings is 6.3 (2)°. The N - C - C - N torsion angle is 177.5 (2)°. In the dianion, the Cr VI ions are in a slightly distorted tetra-hedral coordination environment and the bond angles at the independent Cr VI ions are in the ranges 105.93 (10)-110.60 (11) and 107.35 (11)-111.07 (12)°. The Cr - O - Cr angle is 127.96 (12)°. The crystal used was an inversion twin with refined components of 0.510 (19) and 0.490 (19).