Re-Os and Lu-Hf isotope constraints on the origin and age of pyroxenites from the Beni Bousera peridotite massif: Implications for mixed peridotite-pyroxenite mantle sources

Abstract

A suite of pyroxenites from the Beni Bousera peridotite massif, northern Morocco, have been analysed for Re-Os and Lu-Hf isotopic compositions. Measured sections of the massif indicate that pyroxenite layers make up between 1 and 9% by volume of the total outcrop. Clinopyroxenes from two Cr-diopside pyroxenites have unradiogenic Hf isotope compositions (εHfi ∼ -7.7 to -8.5) whereas those of the Al-augite suite are more radiogenic (εHfi 9.4 to 25.6). In general, the Nd-Hf isotope compositions of the pyroxenites lie close to the mantle array. One garnet pyroxenite lies significantly below the mantle Hf-Nd isotope array such that it requires an ancient history characterized by high Lu/Hf and Sm/Nd but low Lu/Hf relative to Sm/Nd. As with the Sm-Nd and Rb-Sr systems, parent-daughter and isotopic ratios for the Lu-Hf system have been recently decoupled by a partial melting event associated with transfer of the massif from mantle to crust. This created highly fractionated Sm/Nd and and Lu/Hf ratios in many rocks and the pyroxenites can be referred to as 'residual'. The near-solidus extraction of a siliceous melt from the pyroxenites is also a possible explanation for the orthopyroxene-rich margins to numerous pyroxenite layers, via reaction with peridotite. Pyroxenite Os isotope compositions are much more radiogenic than their host peridotites. In contrast to the non-systematic Nd and Hf model ages, a large portion of the pyroxenite Re-Os model ages cluster between 1.2 and 1.4 Ga, within error of the model ages defined by many Ronda pyroxenites and close to the precise 1.43 ± 0.07Ga Lu-Hf isochron defined by clinopyroxenes from the peridotites. The Re-Os system thus seems to have been more robust to late-stage melting events that decoupled Sm/Nd and Lu/Hf isotope systematics in the pyroxenites. In contrast to pyroxenites measured from Ronda, some Beni Bousera pyroxenites have relatively radiogenic Os isotope compositions at high Os concentrations (0.18 to > 2 ppb), comparable with values reported for some cratonic pyroxene-rich xenoliths. In contrast to cratonic eclogites, most pyroxenites analysed here and those reported in the literature lie close to the mantle Nd-Hf isotope array. The Nd-Sr-Pb-Hf isotopic compositions and stable isotope characteristics of these pyroxenites reflect signatures from recycled oceanic crust and sediment. Hence, mixing of such material, if present within the convecting mantle, with peridotite, could account for some of the heterogeneity seen in oceanic basalts. Small amounts of pyroxenite incorporated into peridotite can also produce the radiogenic Os isotope signatures evident in the source of oceanic basalts. However, these observations alone do not require pyroxenite to be an integral part of the convecting upper mantle magma source region. The spectrum of Nd, Hf and Os isotope compositions also makes them a suitable component to explain some of the isotopic characteristics of the source regions of ultrapotassic magmas.