Abstract
What a difference a ligand makes! The reactivity of Pd 0/trialkylphosphane complexes is of great interest because of their unusual effectiveness as cross-coupling catalysts for alkyl electrophiles [Eq. (1)]. This study sheds light on various aspects of the critical oxidative-addition step of the catalytic cycle.
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Hills, I. D., Netherton, M. R., & Fu, G. C. (2003). Toward an Improved Understanding of the Unusual Reactivity of Pd 0/Trialkylphosphane Catalysts in Cross-Couplings of Alkyl Electrophiles: Quantifying the Factors That Determine the Rate of Oxidative Addition. Angewandte Chemie - International Edition, 42(46), 5749–5752. https://doi.org/10.1002/anie.200352858
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